Rubber isn’t actually air tight. It’s just mostly air tight. When you are talking air that is made up of just atoms and very, very small and simple molecules, the very large molecules of the rubber don’t seal well enough that a few atoms can squeeze through occasionally.
Rubber at the molecular level is somewhat like weaved cloth. Where the rubber doesn’t quite weave together perfectly atoms can pass. The more pressure in the tire, the more the flaws get exposed and the more energy there is to push the tiny molecules in the air through.
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