When you think on a microscopic level, the elastomers in the tire actually have holes between the molecules — large enough to let some air molecules through.
Balloons are a great illustration of this. A balloon full of air will “shrink” slower than one full of Helium, which has a much smaller molecule.
Decades ago, for an outdoor event I was at, bought a tank of hydrogen to fill balloons. It worked great — but leaked through the rubber fairly quickly. Half an hour after inflation, they wouldn’t hold themselves up.
A side note. A “Helium Leak Test” is often performed on critical metal instrumentation/components. If there are faulty welds, the helium will leak through the tiniest of spaces and is easily detected.
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