Imagine you heat oil to 150ºC. It doesn’t boil, but it’s really hot. Now you pour water on it. The water heats above 100ºC really, really fast. So fast that it’s an explosion, which is just gasses expanding really fast.
Now, you heat up water to 100ºC. Now you pour oil on it. The oil heats up to 100 degrees really fast, but it doesn’t turn into gas, so it doesn’t explode.
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