Oil outputs a lot more heat and it is suddenly applied to the surface of the object. Water boiling takes a bit more of time to heat, to penetrate the core of whatever you are boiling ( like an egg ) . So the molecular changes are different. They switch different from one structure to another . Slow heating gives the molecules some time to organize better so it they form a more smooth surface. Strong heating, like oil is vs water in this case, is more chaotic at a molecular level so they have less time to organize and end up crystallizing ( which is not the most accurate term but I hope it helps in the visual understanding ) .
Getting something crispy requires getting all the water out of it. By definition, you can’t get all the water out of something by cooking it in water. When water hits 100 C, it boils, but it will never get hotter than that. Oil will get hotter than 100 C, so it will make the water in the food boil out. When you are frying something, you are really just cooking all the water out of it.
It seems nobody mentioned the Maillard reaction. This is the process where food is browned and becomes crisp from cooking. This happens at around 140 C. Water boils at 100 C and will essentially ensure the food in the water can never get hot enough for this reaction unless all the water boils away. Olive oil boils at 180 C, so browning can happen easily.
Heat. Water can’t “burn” or even let things burn inside of it. Oil can get much hotter than water and can cause burning.
Heat breaks down molecules that we consider tough. Plant and animal cells, organic chemistry. This is why you can fry something and it will still turn out juicy inside.
The reason we put breading on things that we fry is to create an oil/water barrier. If you fry a naked piece of chicken the water will all evaporate out. The breading slows the water from steaming out.
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