Why does chocolate only melt smoothly in a pot inside hot water, but not in a pot that is directly heated?

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Why does chocolate only melt smoothly in a pot inside hot water, but not in a pot that is directly heated?

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Because it burns. When the chocolate is in a pot over boiling water, its temperature never rises above the water’s temperature, which is 100°C. When placed directly over the heat, it can pass 200°C, where the chocolate burns.

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