When you freeze food, the water inside the cells expands and ruptures the cell walls. When you defrost it, the ice turns back into water, and the cell walls don’t get repaired – so you get that soggy mush as the water escapes the cells.
Most bread, however, is fairly low in water content. Especially if it’s allowed to go a bit stale before freezing. Therefore, less damage is done to the cells during the freezing process, and the bread won’t go soggy as a result.
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