Most mouth washes have alcohol in them. That alcohol burns the mouth as you use it. Most people only feel a slight burning sensation, but some people are very sensitive to it. You can buy alcohol free mouthwashes and not have that problem.
Another common thing is cinnamon. Cinnamon can burn the inside of the mouth. Like alcohol, some people are more sensitive to Cinnamon. If you are, get a different flavor and try that.
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