Poop is whats left of food after digestion, so any capsaisins lert might still burn.
Urine is water and waste what is filtered out of your blood, only things that linger on blood may passed that way, so aspargus gives a sulfuric smell to pee because its still in urine.
Also you need nerves to feel burn.
Most irritants that are safe to eat aren’t water soluble. Even the few that fall into that exception get further neutered by the processes in your digestive system, from saliva to acid to enzymes. Your body carries chemicals around on your water based blood, so if a chemical survived all that and then got into the bloodstream, you’d have an unpleasant time right away.
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