Generally it’s because when you pour the first batch, you also had just applied some type of oil/butter to “prevent them from sticking to the pan”.
Not only does this change the entire temperature, it also cooks along with the pancakes.
Unless you are applying oil/butter before you pour each batch of pancakes, you aren’t going to get the oil/butter cooking directly under the pancakes.
Source: former short order cook that has cooked thousands of pancakes.
I notice this with any food that browns– such as searing meat. The first batch takes longer to brown.
Someone else said “not the same amount of butter each time”, but my take is this: the first batch leaves browned bits on the pan– you might not see these. The next batch picks these up while making its own as well. Also, the oil/butter that you use will also cook further and make an addition to browning that doesn’t happen when it’s fresh.
If you clean the pan between batches, you won’t see the extra browning, so it has to do with the cleanness of the pan.
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