Because suction cup materials are usually very soft and flexible, but also have tiny, microscopic imperfections in them. On their own, those imperfections would allow air to pass the edge and get into the cup and well, then you wouldn’t have a suction cup any more.
Water has two important properties, it’s both *adhesive* and *cohesive.* This means it both likes to stick to itself, and it also likes to stick to other materials. So a little bit of water will stick to the tiny imperfections around the lip of the suction cup and form a barrier that the air can’t get past. Then when you press the suction cup down you push the air inside the cup part out creating a partial vacuum. The vacuum means that the pressure of the air outside the suction cup will push it down onto the material forming a seal.
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