You have a huge amount of kinetic energy. Like with a nuclear explosion but scaled up incredibly it threw millions of tons of debris into the air. The bigger pieces of debris quickly fell back onto the earth creating other smaller impacts. The sheer friction of all those pieces reentering the atmosphere heated the planet up like an oven so much of the surface was literally cooked. Then the smaller particles from the initial impact lingered creating a long, long winter and it blocked out the sun. This causes plants to die off.
There have been times that a big volcanic eruption caused mild global cooling for a short period of time. But the asteroid impact 65 million years ago was vast compared to a single volcanic eruption
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