From what I have seen, the frost comes from above.
I’ve seen some places where an awning has made a frost shadow, you’d see a clear line following under whatever was on covering it.
These were 8-10 foot from the ground, so it seems like frost forms from cold air and moisture dropping straight down.
Anything at an angle to that will have less, and vertical sides usually have the least.
Everything around your car radiates heat, warming what is pointed at those things. The side windows are pointed at warm buildings or other objects and warmed by their heat radiation. The windshields develop frost because they are pointed at the one thing that isn’t radiating heat: the sky. This allows the temperature of the windshields to drop below freezing.
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