If air comes in it creates an overpressure in the car, which has to go somewhere. So air comes in and goes straight out after. This makes the horrible „wub-wub“ sound. So if you want your air to come in evenly, you have to open a second window, preferably in the back to get rid of the overpressure.
Edit: This is also the reason your ears sometimes pop when you open your window.
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