They only break down starches, but they do that fairly well.
If you spit into a starch-thickened sauce (or less grossly, use the same tasting spoon twice) the sauce will slowly break down and become runny.
There were old traditions, in South America, Japan, and old Norse at least, of chewing and spitting grains to break down the starch so it could be fermented. Malting (sprouting grains so they make starch-dissolving enzymes) has, perhaps happily, replaced that tradition.
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