Vitamins are molecules that your body needs in small quantities, but as a rule of thumb it can’t produce them on its own. They are absorbed in your intestine and enter the bloodstream, they aren’t caloric but your body uses them for other processes.
Fibers are molecules that your body can’t digest and absorb, so they go in and come out mostly unchanged. They are useful because they change the composition and texture of your feces, letting them flow better but also making them more solid.
There are two types of fiber, soluble and insoluble. Iirc soluble fibers make your feces flow better in your intestine, while insoluble fibers make your feces more solid. If you have trouble pooping you need soluble fibers, if your poop is too liquid or dispersed you need more insoluble fibers.
Hope this helps.
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