You’re comparing natural decay with induced fission.
In ambient conditions, radioactive elements with unstable atomic structure are basically falling apart slowly. In turn, they only released a small amount of energy as they do so.
With fission, you speed up the process by shooting a bunch neutrons at the radioactive atoms so they fall apart much, much faster. So much faster that neutrons in the radioactive atoms explode out, hit other atoms and cause them to break apart too. If the effect is strong enough, you get a chain reaction that produces a lot of energy (but also causes all your radioactive fuel to “fall apart” faster).
Natural decay is a rickety building falling apart slowly over years or decades into rubble. Fission is when you topple that rickety building so that it hits the rickety building beside it, which then also tips over and hits another building, and another, etc. domino effect.
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