Classically, molecules generally moves in straight lines until they collide with other ones. When they collide, they change directions (and speed).
So you can pretty much imagine a billiards table without the walls. If the walls of a billiards table didn’t keep the balls within the table, where would they tend to go? Outwards from the center of the table. It helps if you think of a lot of balls within a billiards table rather than just 15.
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