short answer: almost all the plutonium we have is manufactured in a nuclear reactor.
longer answer: radioactive elements, basically, are unstable. they want to fall apart into a more stable format. when uranium is used in a reactor, it undergoes fission (splitting), with the atom shedding protons and neutrons in an attempt to reach a more “stable” state.
One of the decay chains leads to Plutonium, a more unstable and radioactive material than uranium, which makes it possible to make smaller bombs form it as you need less materail to reach critical mass.
this higher instability is why its extremely rare in nature. it decays into something else.
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