Cooling blankets do exist – in healthcare they exist to actively cool patients (for example after cardiac arrest). There just doesn’t seem to be a public demand for cooling blankets so you don’t see them in shops.
edit; I can’t find the name of the cooling blankets we used to use in the ICUs I work in, which used a refrigerated pump to pump cold water into a top and bottom blanket to cool patients. Nowadays we use a device called the Arctic Sun, which uses pads with refrigerated water.
Most cooling systems work by evaporation – either open cycle (swamp cooler evaporating water) or closed cycle (air-conditioning unit evaporating freon) . Indeed the natural way humans cool is by evaporating their perspiration. You can make a simple swamp cooler by lying with a damp towel over you, but plumbing your bed into the aircon is a bit harder.
The other way to cool is using the Peltier effect but I don’t think we can do that with flexible materials (to make a bed cover) yet.
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