eli5: Why do some liquids dry faster than others?

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Like, why do alcohols evaporate faster?

Are liquids that take longer to dry ‘wetter’ than others?

In: Chemistry

4 Answers

Anonymous 0 Comments

Water molecules really like to stick together. Alcohol molecules not as much.

Imagine a group of people dancing. That’s a liquid. Each person moves around within the group, but mostly everyone stays inside the group. Sometimes, especially if the dance is very exuberant (maybe imagine a mosh pit), a person goes shooting out of the group. That’s evaporation: a liquid molecule has joined the air. The air (or other gases or gas mixtures) is more like a bunch of strangers running around at great speed in a big empty room. They don’t stick together, just sometimes bump into each other.

When the liquid is water, imagine the people dancing are very fond of each other. Maybe imagine them holding hands or hugging a lot and then letting go again. It’s hard for a single person to break free from a group like that. Alcohol, or other more *volatile* liquids, is like people who don’t like each other very much. Yeah they’re dancing, but they don’t hold hands, or not as often. So when the dance gets exuberant (people moving around at high speed), it’s much more likely in this less lovey-dovey group for a person to come shooting out.

(An exuberant dance, with people/molecules moving around at high speed, corresponds to a higher temperature. A person can break free of the group at any temperature, but it’s more likely if everyone is moving a lot anyway. If the temperature gets hot enough, then no amount of hand-holding will keep the group together. That’s boiling. When the group boils, they have to break apart and all will turn to gas (eventually). Below the boiling point, some people will leave the group, and some will come back in, and there’s a balance of dancing and running people, with more dancing and fewer running people as the temperature falls. If it gets very cold indeed, then the people stop dancing and just stand there shaking and holding hands continuously.)

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