Different molecules, different chemistries, but the same sensory receptor.
Wasabi and horseradish get their effect from a volatile sulfur-based compound. This means it’s carried very easily into your nasal passages and throat by normal airflow, where it binds to those receptors and gives you the distinct pungency.
Chili/Currys and similar foods contain oily capsaicin, which binds to the receptors in the mouth and isn’t wafted up into other areas as much.
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