Is is not reflected vs nonreflectded sunlight but if warm air that is lighter escape or not.
So the sun gets warmer because the light gets in and heat up the car and the air. The air can’t escape so it gets warmer. Open the windows and the air have a simpler time to escape and it is cooler.
It is also that you are surrounded by the hot part of the car that emits IR light that heat you up. On an open area, it might just be the ground below you you are colder.
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