While EQing can help, you’re correct that there is far too much overlap for this method to be really successful on its own unless you’re looking for something that sits in its own range of a song that’s mixed well, like bass. For vocals, the most common practice relies on how most vocal music is mixed; vocals down the center, instruments panned to the sides. By converting a stereo track to left and right mono signals, phase inverting one side, then playing them back together, you’ll cancel out everything down the middle; typically just the lead vocal. By inverting an instrumental track over the original full mix, you can isolate a vocal. There’s many tutorials out there on YouTube, and it’s definitely a fun way to play with audio!
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