How do we know that burning a dehydrated amount of food and measuring the temperature change is an accurate way of determining a calorie?

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I understand that we dehydrate the food and put the known amount of dry food into a known amount of water then ignite the food then measure the change in water temperature to determine the number of calories in it.

What I don’t understand, is how we know that that is an accurate measurement of our body’s ability to digest food and absorb the energy from it.

Moisture can’t be the only variable for determining flammability and energy output, right? If I ball up a piece of paper before igniting it, it’s going to burn at a different rate than if I don’t, with no change in moisture. I feel like the cellular/molecular/macro structure, flammability, ignition point, etc. all have to be taken into account. Is it? Because it’s never mentioned on any article about how calories are measured. What about if something takes longer to burn at a lower temperature vs something that erupts into flame at a high temp and is gone instantly? Even if it’s the same amount of energy being released, if it’s over a different amount of time, wouldn’t that affect the relative temperature of the water at the time it’s being measured?

The body absorbs trace amounts of iron and needs it for survival, but if I try to set a 1 gram iron ball on fire, wouldn’t i need a higher ignition point, and so by the very virtue of that be increasing the minimum temperature of the water before I even begin to receive energy from the burn?

I imagine there’s some part of this mechanism that I’m just not aware of, or misunderstand, but I can’t think of that it would be.

Also, yes, i realize that nowadays we use a different method that is basically just math derived from what we already know about calorie content, but how did we determine *that*? By setting it on fire, right?

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3 Answers

Anonymous 0 Comments

The energy output isn’t reduced by water, either, the water just makes it harder to burn.

The energy output depends solely on what’s being reacted. The reaction is done fairly quickly and time for the water to lose heat to surroundings is minimal, plus it is insulated.

Our bodies’ ability to process those calories has nothing to do with the fact that they are there, though, and so they are on the label.

Anonymous 0 Comments

food carries energy in the form of chemical bonds that exist between atoms in the molecules that make up the food itself.
moisture is a variable and they do this because water tends to absorb a lot of heat and that could mess with the measurements.
measurements are done with a calorimeter and is essentially a highly insulated chamber that will keep outside sources of heat to a minimum.
about your statement on iron: while there is about 20 g worth of iron in the body at any one time, your body likes to hang onto it and instead the food carries the “trace amount” is what is ingested every day due to it being recycled efficiently.
using trace amount in a broad sense though, as iron is pretty abundant in meat.

they dont just set the sample on fire. the process of calorimetry gives you an approximation of the total energy that is stored between chemical bonds in a sample of food. they do this by getting the sample to burn, breaking chemical bonds amd releasing energy in the form of heat. the heat released represents the calories IN the food and not the calories that you will absorb if you ingest a similar substance.

Anonymous 0 Comments

Yeah, there are complications. Combusting a sample down to H2O, CO2, etc. will tell you the total amount of energy in a food, which tells you the upper limit on how much *you* could get from it.

But how much you *will* get from food depends on more than that. A gram of sugar will be consumed much, *much* more efficiently than a gram of cellulose. And cooking can make food more digestible, e.g. converting collagen into gelatin.

https://en.wikipedia.org/wiki/Food_energy