Your question is more a matter of language than chemistry:
_All_ carbohydrates _are_ sugars: sucrose, glucose, fructose, lactose, galactose, dextrose — you name em. They all belong in the saccharine category, and saccharine come from the Greek word for sugar: zachari.
However, when people talk about _sugar_, they almost exclusively refer to table sugar, which is a mix of fructose and glucose.
So to answer your two questions: bread doesn’t turn into sugar, it _is_ sugar — just not the same sugar as what you put into your coffee; and carbs _are_ sugars, but people simply refer to a particular few of them when they say that word.
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