Air pressure differences.
The top sunroof is pointed away from the flow of air, but that air is at a mostly normal pressure. The rear window is getting less pressure applied to it from the air outside, as it is trailing behind the vehicle. There will always be an area of lower pressure behind a moving vehicle, unless there’s some weird aerodynamics going on.
If you have two holes in a box, and one of those holes has less pressure around it that the other (from the outside), the air will flow from the first hole to the second one.
That’s basically what’s happening. Even though the sunroof is angled away from the wind, it still has more air pressure coming through it that the rear window does. That difference causes air to come in from the top, and flow through the back. You’re basically turning your car into a very complicated wind tunnel.
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