The packs contain a liquid (actually a gel, usually made from a solution of sodium acetate) which has the property that it releases heat when crystals form in it.
When you flex the disc it simply causes a sudden sharp point to occur within the substance. This is enough to start the crystallisation process which then rapidly spreads throughout the entire gel. It therefore heats itself up and then gradually emits that heat over the next hour or so as it slowly cools down.
Latest Answers