You’re thinking of mixing paint where yellow+blue=green. With light color mixing works differently – it’s red+green=yellow. If you add blue to that (red+green+blue) you actually get white.
Because your eyes are based on seeing light they see the red green blue light mixing.
If you open a paint program on your computer you can experiment with how red green and blue light mixes using the color picker, because monitors also work by red green blue light.
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