Most food has water in it, and some of that water is boiled away when you heat it- that’s most of the shrinkage. That’s why a hamburger patty or a roasted vegetable is going to shrink when you cook it.
Then think about pasta or rice. Those increase in size when you cook them- because they start dry and then absorb more water.
>If matter expands when heated, why does most food shrink when being cooked?
For the same reason you won’t end up with a bigger house when you burn it down.
Your food (and most any thing around you) isn’t just “matter”, it’s a complex structure, a type of building. Multiple different buildings with unique structures and characteristics, in fact!
Denature the proteins, boil off the water, break down the cell walls… there are many ways to destroy those buildings via heat – you’re not merely making them *warm*.
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