Water is a very interesting chemical. When liquid the molecules of H2O can move around freely whereas, when solid, the molecules are held in place by intermolecular forces. As a liquid the molecules are able to be close together but when it decreases in temperature those intermolecular forces hold the molecules apart. Water is most dense at about 4 degrees Celsius. Any hotter and the water expands, any colder and the forces hold molecules apart.
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