Some body operations stop upon death. The simplest example is breathing. If someone is found in water, but there is no water in the lungs, they weren’t breathing underwater, meaning they didn’t drown. If someone was in a fire, but has no soot in the lungs, they were dead before the fire.
For your example, certain things that happen when a dead body is shot compared to when a live body is shot. For example, you lose more blood if you are shot while living, because your heart is still pumping, and you lose some blood before dying. If you were poisoned first, you lose less blood.
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