Oxygen in water is aqueous. Which means it’s completely dissolved. Typically we breath oxygen as 2 molecules bonded together. However in water those bonds break and it ionizes. Turning 2 bonded oxygen into 2 separate oxygen molecules each with a slight electrical charge.
Our lungs can’t handle that kind of oxygen. The same way fish can’t handle our airborne O2.
Water contains oxygen atoms. Oxygen molecules which is what you need to breathe also contains oxygen atoms. But water and oxygen is very different compounds. This is like saying that if your house is made of wood, why can’t we just live in the woods instead of a house. They do share one common component but they are very different from each other.
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