Good aluminum or iron ore deposits are about 40-60% metal, with the remainder being oxygen atoms and maybe a bit of other simple minerals.
Municipal solid waste is about 9% metals, and that 9% is a mix of aluminum, steel, zinc, copper, tin, etc. It’s mixed in with huge amounts of organic matter, plus lots of other contaminants. And the metals aren’t pure metals: they’re usually alloys with a wide range of added elements.
The chemistry needed to separate such tiny amounts of metal from such a complex molecular stew would be really difficult.
It’s much easier to separate out the metal before it gets mixed into the trash, which is what recycling is all about.
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