Positive and negative charges in chemistry are really just positive and negative charges in physics. To explain why protons are positive and electrons are negative requires some light quantum physics, but it doesn’t ultimately have a satisfying answer.
The law that opposite charges attract and similar charges repel is just a law of the universe, and one of the four “interactions” that make up reality itself. Without that rule, most if not all of what we understand about matter doesn’t actually make sense.
The tl;dr is that nothing “happens” to make certain particles positive versus negative. They just are.
Though, I think this is a bit complex for a 5-year old 😛
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