They’re working on it. But the way it happens in plants is that an entire organism revolves around the process and keeps up with the needs until it can’t anymore and dies. And a lot of that is done on a microscopic scale with a pretty small energy excess which the plant uses to grow. From an engineering standpoint it’s more valid to take lessons from plants then to try to reinvent them. They can teach us a lot about optimal use of light energy.
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