If you burn something, that means you charred it unintentionally. Something like noodles, cake, etc. that you don’t want that type of flavor involved in. You can also burn foods you do normally char (like meats or peppers) but that requires basically going too far with the char. It revolves around the flavor of the food and how it changes when that happens (this is also excluding the smoky flavor you may get from say a wood grilled char).
Ultimately two different words that mean the same thing, but in different flavor contexts. A bit of char on a marshmallow or a bell pepper is good, a bit of char on your lasagna is not good.
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