Your body doesn’t actual sense temperature but differences in temperature. Well, more specifically it sense the rate of heat transfer. And that is directly proportional to differences in temperature. The higher the difference in temp the higher the rate of heat transfer.
So if you hands are cold and you use hot water that’s a big temperature difference. So you perceive it as extra hot.
It’s OK to use out-of-the-tap hot water. The pain you feel is just your body re-calibrating. Where people get in trouble is that they use water that’s hotter than hot tap water, and they ignore the pain because they figure it’s just the re-calibrating. But you can damage yourself **really** badly, just like how you could damage yourself on a normal day by pouring scalding-hot water on yourself.
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