> Highest density of water is when it’s at 4 degrees.
At normal atmospheric pressure, yes. At extreme pressures, this no longer holds true.
> However, I’ve been told that at very high pressures it’s possible to have solid ice at 79°C. How is that possible?
And even way above that, at least according to https://en.wikipedia.org/wiki/Phase_diagram#/media/File:Phase_diagram_of_water.svg
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