Warmth and temperature are not the same thing.
A candle might be a few hundred degrees, but it doesn’t radiate (much) thermal energy. The wet on your hand will be enough to quell that intense – but small- energy source.
But the hot pan, despite having a lower temperature, is larger, and had more thermal energy in its metal/Pyrex structure. That abundance of heat is enough to shluck through a wet mitt through conduction. The heat from the over pan cannot be quelled by a soggy mitt, so instead that thermal energy agitates the water, making it hot, and soon enough the heat conducts through.
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