B is easily confused for blue (RGB color), so a different letter is used.
K also is generally understood to mean Key plate, (black provides sharp detail/contrast and is the most noticible color and so when someone is manually aligning different color plates it’s the most critical (key) one) though there’s a bit of argument as to if that’s really the case originally. There’s no definitive etymology on this.
In any case it’s likely a combination of these two factors that cemented K as meaning black in CMYK printing.
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