Flour burns aggressively when it’s dispersed, because of its very large surface area (due to very fine milling). When it’s packed into bricks, the available surface area is a lot lower because the particles are packed together tightly and there isn’t a lot of air (i.e. oxygen) between them. So if you hold a lighter up to a paper-bagged brick of flour it may catch on fire but it won’t be an instant explosion like what you’d get at a flour mill where there is flour in the air and spread out all over the place
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