In theory, yes, it will. Can you source pure ethanol? Unless we’re cheating and buying something from the liquor store, or unless we somehow have a guy for medical ethanol, yes, there will be additives that will kill you. This is how they avoid taxation.
Next problem: 100% ethanol kind of isn’t a thing. Distill it to 97.2% and it stops getting purer, becoming what’s called an azeotrope.
But you can do fractions, and find a correct number of parts of water to add to your 97.2% to get that 80 proof. It won’t be 3:2, but it’ll be close.
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