Sparks are just hot pieces of things (usually metal), and they just happen to be glowing in that temperature range to produce red to white light. “Electricity” is that white/blue/sometimes purpleish color when it arcs because it’s actually turning certain elements in the air into a plasma. The arc is so hot it’s ripping electrons off the atoms, ionizing the gas, and the color light it gives off (called it’s emission spectrum) is that bright blue color.
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